Reporters asked Biden if he would see himself personally sanctioning Putin if he invaded Ukraine.

"Yes," he said. "I would see that."

A U.S. plane carrying military equipment and munitions landed in Kyiv on Tuesday, the third shipment of a $200-million security package to shore up Ukraine.

The U.S. Defense Department has said about 8,500 U.S. troops have been put on heightened alert and are awaiting orders to deploy to NATO's eastern flank. Biden said on Tuesday he may move the troops in the nearer term.